当前储能技术的总趋势是实现高能量密度和高安全性。在各种储能体系中,水系锌锰电池(ZMAB)因其低成本、高安全性、良好的电压平台和可观的理论容量而备受关注。到目前为止,各种高能、长期稳定的ZMAB已经被广泛开发,并表现出巨大的应用潜力。但与电池性能提高同时存在的是对ZMAB的复杂反应化学原理的争议。本文通过“pH线索“给出Mn (II) ↔ Mn (III) ↔ Mn (IV)的转化,及质子消耗/生成规律,从而在离子/分子/团簇尺度上讨论化学原理并给出实用的调控措施。
近日,Advanced Materials上发表了题为“Protocol in Evaluating Capacity of Zn–MnAqueous Batteries: A Clue of pH”的观点文章。复旦大学晁栋梁等人概述了ZMAB的发展历程和目前已取得的主要成就,同时也提出目前存在的主要问题,即由于多相、多价态和不同电解液(质)所导致的储能机理不明晰。为此作者总结了电极/电解液(质)主导的反应原理,并给出对应的量化分析方法。此外,作者还对下一阶段的研究方向给出建议。
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